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Periclase [MgO]
Structure Cubic
Space Group Fm-3m (No. 225)
a=4.1900 Å
Z=4
Atomic Positional Parameters
Reference
E Schiebold (1921) Zeitschrift
fuer Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie,
56, 430
Mineral Chemistry
Periclase (MgO), which has a similar structure to that of halite, is usually formed in high-temperature metamorphism and decarbonation of dolomites and magnesian limestones. Up to 8 weight percent of FeO may substitute for MgO in this phase.
Characterisation of the behaviour of (Mg,Fe)O solid solutions is crucial for understanding the lower mantle, and many experimental and theoretical studies of MgO under lower mantle conditions have been made. It is likely that the composition of the lower mantle of the earth is made up of a silicate perovskite (Mg0.9Fe0.1)SiO3, with several percent Al2O3, coexisting with (Mg,Fe)O - magnesiowüstite.