![]() |
Rutile [TiO2]
Structure Tetragonal
Space Group : P42/mnm
(No. 136)
a=4.5937 Å c=2.9587
Å
a=b=g=90.00
Z=2
Atomic Positional Parameters
Reference
Gonschorek W and Feld R (1982) Zeitschrift fuer Kristallographie,161, 1
Mineral Chemistry
Rutile, anatase and brookite are polymorphs of TiO2, and have Ti4+ cations coordinated by six O2- anions. In rutile, these TiO6 octahedra are linked by edges to form chains parallel to the z-axis.
Rutile structured minerals include pyrolusite (MnO2), cassiterite (SnO2) and plattnerite (PbO2).
Rutile, the high-temperature polymorph of TiO2, is formed in igneous and metamorphic rocks. It may be found in eclogites, in pegmatites, and in quartz and apatite veins. Fine needles of rutile may be present in clays and shales.
The CHIME figure shows titanium atoms coloured grey, and oxygens coloured red. The unit cell
is outlined.